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61.
Zahra Mosayebzadeh Reza Ansari Majid Arvand 《Journal of the Iranian Chemical Society》2014,11(2):447-456
In this study, a potentiometric sensor based on a pencil graphite electrode (PGE) coated with polypyrrole doped with Titan yellow dye (PPy/TY) was prepared for potentiometric determination of magnesium ion in aqueous solutions. The structural characteristics of magnesium sensor electrode (PGE/PPy/TYMg) were studied using scanning electron microscopy and Fourier transform infrared along with energy-dispersive spectroscopy. Under the optimal conditions, the electrode reveals a good Nernstian behavior with slope of 28.27 ± 0.40 mV per decade over the concentration range of 1.0 × 10?5–5.0 × 10?2 M and a detection limit of 6.28 × 10?6 M. The potentiometric response of fabricated electrode toward magnesium ion was found to be independent of the pH of the test solution in the pH range of 4.5–8.0. The electrode showed fast response time (<10 s) and good shelf lifetime (>2 months). The prepared magnesium sensor electrode can also be used as an indicator electrode in potentiometric titration of Mg2+ with EDTA with distinguished end point. The electrode revealed good selectivity with respect to many cations including alkali, alkaline earth, transition and heavy metal ions. The introduced magnesium electrode was used for measurement of Mg2+ ion in real samples without any serious interferences from other ions. 相似文献
62.
Journal of Cluster Science - In this research, we used a fast and simple method for synthesis of calcium titanate (CaTiO3) and calcium ferrite (CaFe2O4) nanostructures: microwave assisted... 相似文献
63.
A new high: Cannabis as a budding source of carbon-based materials for electrochemical power sources
Zahra I. Rana Ami R. Shah Alice V. Llewellyn Katrina Mazloomian Patricia McAlernon Thomas S. Miller Patrick L. Cullen Paul R. Shearing Dan J.L. Brett 《Current Opinion in Electrochemistry》2022
Cannabis sativa L., a low-cost, fast-growing herbaceous plant, is seeing a resurgence in widespread cultivation as a result of new policies and product drive. Its biodegradable and environmentally benign nature coupled with its high specific surface area and three-dimensional hierarchal structure makes it an excellent candidate for use as a biomass-derived carbon material for electrochemical power sources. It is proposed that this ‘wonder crop’ could have an important role in the energy transition by providing high-functioning carbon-based materials for electrochemistry. In this article, all instances of C. sativa usage in batteries, fuel cells and supercapacitors are discussed with a focus on highlighting the high capacity, rate capability, capacitance, current density and half-wave potential that can be achieved with its utilisation in the field. 相似文献
64.
Kamyabi Mohammad Ali Alipour Zahra Moharramnezhad Mohsen 《Journal of Solid State Electrochemistry》2021,25(2):445-456
Journal of Solid State Electrochemistry - Here is reported a new feasible and facile method for the determination of amoxicillin by the electrochemiluminescence (ECL) method. The ECL signal was... 相似文献
65.
Structural Chemistry - The measured densities and viscosities of the binary mixtures of the isobutanol and 2-methylcyclohexanol were reported experimentally in a certain range of concentrations at... 相似文献
66.
Safari Nasimeh Imanzadeh Gholamhassan Asgharzadeh Roghayyeh Hosseyni Seyyedeh Tahereh Shamkhali Amir Nasser Soltanzadeh Zahra 《Chemistry of Heterocyclic Compounds》2021,57(6):640-645
Chemistry of Heterocyclic Compounds - In this work, new pyrazole derivatives were prepared by one-pot three-component reaction emloying symmetric and asymmetric 1,2-disulfonyl-hydrazines,... 相似文献
67.
68.
The behaviour of a dislocation pileup with a finite-strength source is investigated in the presence of various stress gradients within a continuum model where a free-dislocation region exists around the source. Expressions for dislocation density and stress field within the pileup are derived for the situation where there are first and second spatial gradients in applied stress. For a pileup configuration under an applied stress, yielding occurs when the force acting on the leading dislocations at the pileup tips reaches the obstacle strength, and at the same time, it is required that the source be at the threshold stress for dislocation production. A numerical methodology is presented to solve the underlying equations that represent the yielding conditions. The yield stress calculated for a pileup configuration is found to depend on stress gradients, obstacle spacing and source/obstacle strengths. It increases with increasing the first stress gradient, yet dependent on the second stress gradient. Furthermore, while the dependency of yield stress on the obstacle spacing intensifies with increasing the first stress gradient, it diminishes with an increase of second stress gradient. Therefore, the second stress gradient, as a newly introduced parameter, can provide a new physical insight into the size-dependent plasticity phenomena at small length scales. 相似文献
69.
Jaber Javidi Mohsen Esmaeilpour Zahra Rahiminezhad Fatemeh Nowroozi Dodeji 《Journal of Cluster Science》2014,25(6):1511-1524
In this study H3PW12O40·9H2O and H3PMo12O40·6H2O (HPA) particles were changed into nano forms by heat-treatment in an autoclave as a simple, repaid, inexpensive and one step method. The particle size of these nanoparticles was around 25 nm. The as-synthesized nanostructures were characterized by dynamic light scattering, X-ray powder diffraction, transmission electron microscopy, Fourier transform infrared spectroscopy and inductively coupled plasma analyzer. Thermal stability of nanoparticles was surveyed by thermal gravimeter analyse. Acidity of prepared nanoparticles was investigated by pyridine adsorption method. Results showed rising acidity by declining particle size of HPA. 相似文献
70.
The hydrogen bond strength, molecular geometry, π-electron delocalization, and physical properties such as dipole moment, chemical potential, and chemical hardness of 4-nitropyridine-3-thiol and its 29 derivatives have been studied by means of density functional method with 6-311++G** basis set in gas phase and water solution. Also, the excited-state properties of intramolecular hydrogen bonding in these systems have been investigated theoretically using the time-dependent density functional theory method. The HOMA, NICS, PDI, ATI, FLU, and FLUπ indices as well-established aromaticity indicators have been examined. Natural bond orbital analysis is also performed for better understanding the nature of intramolecular interactions. The electron density and Laplacian (?2 ρ) properties, estimated by AIM calculations, indicate that H···O bond possesses low ρ and positive ?2 ρ values, which are in agreement with electrostatic character of the HBs, whereas S–H bond has covalent character. Numerous correlations between topological, geometrical, and energetic parameters are also found. 相似文献